Armenian champion Yerevan's Pyunik lost to Serbian champion Crvena Zvezda with a score of 0-2 in the return match of the third qualifying round of the Champions League.
Gabonese midfielder Guelor Kanga and Serbian striker Milan Pavkov scored.
In its first game, Pyunik suffered a 0-5 defeat.
Pyunik will continue to fight in the play-offs of Europa League, where they will meet with Sheriff Tiraspol.
The matches of play-off of Europa League will be held on August, 18 and 25.
Champions League third qualifying round, return match
Pyunik vs Crvena Zvezda - 0:2 (0:5)
Guelor Kanga, 44 (penalty kick), Milan Pavkov, 60
Penalty kicks: Aleksandar Katai 30, 11